Eclectic actress and gossip-column favorite dethrones media maven Oprah Winfrey atop this year’s Celebrity 100. Jolie has always been able to attract tabloid attention and Oscar nods, but this year, she’s finally figured out a way to make serious money. Her most recent blockbuster, Wanted, proved this mother of six’s sweet spot is action films; the movie earned $340 million at the box office. Up next: Salt, in which Jolie plays a CIA officer accused of being a spy.